powderИзвестия вузов. Порошковая металлургия и функциональные покрытияPowder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya)1997-308X2412-8767НИТУ "МИСИС"10.17073/1997-308X-2016-3-31-42powder-228Research ArticleТугоплавкие, керамические и композиционные материалыRefractory, Ceramic, and Composite MaterialsВЛИЯНИЕ ЛЕГИРОВАНИЯ КАРБОНИТРИДА TiC0,5N0,5 ЦИРКОНИЕМ НА МЕХАНИЗМ ВЗАИМОДЕЙСТВИЯ С Ni–Mo-РАСПЛАВОМEFFECT OF CARBONITRIDE TiC0,5N0,5 DOPING WITH ZIRCONIUM ON THE MECHANISM OF INTERACTION WITH Ni–Mo MELTЖиляевВ. А.ZhilyaevV. A.

Доктор технических наук, кандидат  химических наук, ведущий научный сотрудник лаборатории физико-химических методов анализа ИХТТ УрО РАН.

620990, г. Екатеринбург, ГСП, ул. Первомайская, 91. E-mail: zhilyaev@ihim.uran.ru

Dr. Sci. (Tech.), Cand. Sci. (Chem.), Leading Researcher, Laboratory of physical and  chemical analysis methods, ISSC UB RAS.

620990, Russia, Yekaterinburg, Pervomayskaya str., 91. E-mail: zhilyaev@ihim.uran.ru

zhilyaev@ihim.uran.ruПатраковЕ. И.PatrakovE. I.

Кандидат  химических наук, старший научный сотрудник отдела наноспинтроники ИФМ УрО РАН.

620990, г. Екатеринбург, ГСП, ул. С. Ковалевской, 18. E-mail: patrakov@imp.uran.ru

Cand. Sci. (Chem.), Senior Researcher, Department of Nanospintronics, IMP UB RAS.

620990, Russia, Yekaterinburg, S. Kovalevskoy str., 18. E-mail: patrakov@imp.uran.ru

patrakov@imp.uran.ruИнститут химии твердого тела УрО РАН, ЕкатеринбургРоссияInstitute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, EkaterinburgRussian FederationИнститут физики металлов УрО РАН имени М.Н. Михеева, ЕкатеринбургРоссияM.N. Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences, EkaterinburgRussian Federation201604102016033142Copyright © Жиляев В.А., Патраков Е.И., 20162016Жиляев В.А., Патраков Е.И.Zhilyaev V.A., Patrakov E.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://powder.misis.ru/jour/article/view/228

The paper presents a novel study of the effect of titanium carbonitride TiC0,5N0,5 doping with zirconium on the mechanism and kinetic features of contact interaction with the Ni–25%Mo melt (t = 1450 °C, vacuum 5•10–2 Pa) using the methods of electron microprobe analysis and scanning electron microscopy. It shows the basic effects of a zirconium modifying influence on dissolution, phase and structure formation processes occurring during the interaction between the Ti1–nZrnC0,5N0,5  carbonitride (n = 0,05  and  0,20) and Ni–Mo melt, and  analyzes factors contributing to their occurrence. It was found that  the chemical role of small zirconium additives is similar to the role of nitrogen in many  respects. Experiments confirm the practical absence of zirconium and  nitrogen in the K-phase composition. It was shown that  the Ti0,80Zr0,20C0,5N0,5  zirconium-rich carbonitride cannot be recommended as a high melting component of a ceramic material (cermet) due to the limitations of a chemical nature.

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