powderИзвестия вузов. Порошковая металлургия и функциональные покрытияPowder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya)1997-308X2412-8767НИТУ "МИСИС"10.17073/1997-308X-2017-1-64-75powder-279Research ArticleПрименение порошковых материалов и функциональных покрытийApplication of Powder Materials and Functional CoatingsРАЗРАБОТКА НОВОГО ПОКОЛЕНИЯ РЕЖУЩЕГО ИНСТРУМЕНТА ИЗ СВЕРХТВЕРДЫХ МАТЕРИАЛОВ С НАНОМОДИФИЦИРОВАННОЙ СВЯЗКОЙ ДЛЯ ОБРАБОТКИ СТАЛИ И ЧУГУНАDEVELOPMENT OF NEXT GENERATION DIAMOND TOOLS BASED ON SUPERHARD MATERIALS WITH NANOMODIFIED BINDER FOR STEEL AND CAST IRON MACHININGЛогиновП. А.LoginovP. A.

канд. техн. наук, мл. науч. сотр. Научно-учебного центра (НУЦ) СВС МИСиС–ИСМАН 

Cand. Sci. (Tech.), junior researcher of Scientific-educational Centre of SHS of MISIS–ISMAN

pavel.loginov.misis@list.ruСидоренкоД. А.SidorenkoD. A.

канд. техн. наук, науч. сотр. НУЦ СВС МИСиС–ИСМАН

Cand. Sci. (Tech.), researcher of Scientific-educational Centre SHS MISIS–ISMAN

dsidorenko@inbox.ruЛевашовЕ. А.LevashovE. A.

докт. техн. наук, проф., акад. РАЕН, зав. кафедрой порошковой металлургии и функциональных покрытий НИТУ «МИСиС», директор НУЦ СВС МИСиС–ИСМАН

Dr. Sci. (Tech.), prof., acad. of Russian Academy of Natural Science, head of the Department of powder metallurgy and functional coatings of National University of Science and Technology «MISIS», head of Scientific-educational Centre of SHS MISIS–ISMAN

levashov@shs.misis.ruАндреевВ. А.AndreevV. A.

канд. физ.-мат. наук, ген. директор ЗАО «Кермет» 

Cand. Sci. (Phys.-Math.), executive general manager of CJSC «Kermet»

levashov@shs.misis.ruНациональный исследовательский технологический университет (НИТУ) «МИСиС», г. МоскваРоссияScientific-educational Centre of SHS of MISIS–ISMANRussian FederationНациональный исследовательский технологический университет (НИТУ) «МИСиС», г. МоскваРоссияRussian Academy of Natural Science, National University of Science and Technology «MISIS», Scientific-educational Centre of SHS MISIS–ISMANRussian FederationЗАО «Кермет», г. МоскваРоссияCJSC «Kermet»Russian Federation201721032017016475Copyright © НИТУ "МИСИС", 20172017НИТУ "МИСИС"НИТУ "МИСИС"https://powder.misis.ru/jour/about/submissions#copyrightNoticehttps://powder.misis.ru/jour/article/view/279

Показана возможность использования связок типа Next100, легированных никелем и модифицированных наночастицами WC, ZrO2 и hBN, для изготовления режущего инструмента на основе сверхтвердых материалов, предназначенного для обработки стали и чугуна. Установлено, что легирование связки никелем позволяет увеличить ее ударную вязкость в 2,5 раза и существенно улучшить стойкость сегментов инструмента при эксплуатации. Благодаря введению в связку наночастиц WC, ZrO2 и hBN обеспечивается повышение ее прочности на 100–150 МПа и твердости на 5–7 HRB. В присутствии наночастиц WC возрастает адгезия кубического нитрида бора к связке. Определено оптимальное соотношение монокристаллов алмаза и кубического нитрида бора в рабочем слое, при котором достигаются максимальные служебные характеристики инструмента, – 75 : 25. Выявлены формирование нанокластеров аморфного бора на границе раздела кубического нитрида бора и связки и растворение небольшого количества азота в компонентах связки при горячем прессовании.

 

 

 

 

The paper demonstrates the possibility of using Next100 type binders alloyed with nickel and modified with WC, ZrO2 and hBN nanoparticles for the manufacture of cutting tools based on superhard materials intended for steel and cast iron machining. It was found that nickel alloying of the binder makes it possible to increase its impact strength by 2,5 times and significantly improve the life of tool segments while in operation. Introduction of WC, ZrO2 and hBN nanoparticles into the binder increases its strength by 100–150 MPa and hardness by 5–7 HRB. In the presence of WC nanoparticles, the adhesion of cubic boron nitride to the binder increases. The optimal ratio of diamond to CBN grains in the coating is determined for better tool performance – 75 : 25. The paper reveals the formation of amorphous boron nanoclusters at the at CBN-binder interface, and dissolution of a small amount of nitrogen in the binder components during hot pressing.

 

 

 

 

алмазный инструментрежущий инструментсверхтвердые материалынаночастицымеханические свойствакомпозиционный материалdiamond impregnated toolcutting toolsuperhard materialsnanoparticlesmechanical propertiescomposite materialReferencesSung C.-M. Brazed diamond grid: a revolutionary design for diamond saws. Diamond Relat. Mater. 1999. Vol. 8. Iss. 8—9. P. 1540—1543.Sung C.-M. Brazed diamond grid: a revolutionary design for diamond saws. Diamond Relat. Mater. 1999. Vol. 8. Iss. 8—9. P. 1540—1543.Konstanty J. Powder metallurgy diamond tools. Oxford: Elsevier, 2005.Konstanty J. Powder metallurgy diamond tools. Oxford: Elsevier, 2005.Bakori A., Szymariski A. Practical uses of diamond. War-saw: Ellis Horwood & Polish Scientific Publishers, 1993.Bakori A., Szymariski A. Practical uses of diamond. War-saw: Ellis Horwood & Polish Scientific Publishers, 1993.Sato K., Yokoyama T., Suzuki K. Production of electro-deposited diamond wheels and grinding performance for hard metals and ceramics. J. Mater. Process. Technol. 1996. Vol. 62. P. 303—308.Sato K., Yokoyama T., Suzuki K. Production of electro-deposited diamond wheels and grinding performance for hard metals and ceramics. J. Mater. Process. Technol. 1996. Vol. 62. P. 303—308.Li Y., Li G., Jiang H., He Y. New type of matrix material for the manufacture of electroplated diamond tools. Ind. Diamond Rev. 2002. Vol. 62. P. 259—262.Li Y., Li G., Jiang H., He Y. New type of matrix material for the manufacture of electroplated diamond tools. Ind. Diamond Rev. 2002. Vol. 62. P. 259—262.De Resende L.W., Corat E.J., Trava-Airoldi V.J., Leite N.F. Multi-layer structure for chemical vapor deposition diamond on electroplated diamond tools. Diamond Relat. Mater. 2001. Vol. 10. P. 332—336.De Resende L.W., Corat E.J., Trava-Airoldi V.J., Leite N.F. Multi-layer structure for chemical vapor deposition diamond on electroplated diamond tools. Diamond Relat. Mater. 2001. Vol. 10. P. 332—336.Denkena B., Köhler J., Ermisch A. Wire cutting tool concepts for steel machining. Adv. Mat. Res. 2011. Vol. 325. P. 238—243.Denkena B., Köhler J., Ermisch A. Wire cutting tool concepts for steel machining. Adv. Mat. Res. 2011. Vol. 325. P. 238—243.Tönshoff H.K., Hillmann-Apmann H. Diamond tools for wire sawing metal components. Diamond Relat. Mater. 2002. Vol. 11. Iss. 3—6. P. 742—748.Tönshoff H.K., Hillmann-Apmann H. Diamond tools for wire sawing metal components. Diamond Relat. Mater. 2002. Vol. 11. Iss. 3—6. P. 742—748.Köhler J., Ermisch A., Denkena B. Tool concepts for wire cutting of reinforced concrete. In: 1-st Int. conf. on stone and concrete machining. Hannover, 2011. P. 6.Köhler J., Ermisch A., Denkena B. Tool concepts for wire cutting of reinforced concrete. In: 1-st Int. conf. on stone and concrete machining. Hannover, 2011. P. 6.Amaral P.M., Coelho A., Anjinho C.A., Fernandes J.C., Rosa L.G. Evaluation of the relationship between diamond tool wear performance and the mechanical properties of the individual metallic binders. Adv. Mater. Forum V. 2010. Vol. 636—637. P. 1467—1474.Amaral P.M., Coelho A., Anjinho C.A., Fernandes J.C., Rosa L.G. Evaluation of the relationship between diamond tool wear performance and the mechanical properties of the individual metallic binders. Adv. Mater. Forum V. 2010. Vol. 636—637. P. 1467—1474.Konovalov V.A., Aleksandrov V.A., Levin M.D. Influence of the strength of diamond containment and the rate of abrasive wear of a binder on the serviceability of a diamond-abrasive stone-cutting tool. Sintech. Almaz. 1975. P. 26—28.Konovalov V.A., Aleksandrov V.A., Levin M.D. Influence of the strength of diamond containment and the rate of abrasive wear of a binder on the serviceability of a diamond-abrasive stone-cutting tool. Sintech. Almaz. 1975. P. 26—28.Bogatyreva G.P., Nevstruev G.F., Il’nitskaya G.D., Konovalov V.A., Tkach V.N. The possibilities for improvement of the strength of diamond grit retention in a binder. Sverkhtverdye Materialy. 2001. Iss. 2. P. 20—25.Bogatyreva G.P., Nevstruev G.F., Il’nitskaya G.D., Konovalov V.A., Tkach V.N. The possibilities for improvement of the strength of diamond grit retention in a binder. Sverkhtverdye Materialy. 2001. Iss. 2. P. 20—25.Loginov P.A., Levashov E.A., Kurbatkina V.V., Zaitsev A.A., Sidorenko D.A. Evolution of the microstructure of Cu— Fe—Co—Ni powder mixtures upon mechanical alloying. Powder Technol. 2015. Vol. 276. P. 166—174.Loginov P.A., Levashov E.A., Kurbatkina V.V., Zaitsev A.A., Sidorenko D.A. Evolution of the microstructure of Cu— Fe—Co—Ni powder mixtures upon mechanical alloying. Powder Technol. 2015. Vol. 276. P. 166—174.Tokova L.V., Zaitsev A.A., Kurbatkina V.V., Levashov E.A., Sidorenko D.A., Andreev V.A. The features of influence of ZrO2 and WC nanodispersed additives on the properties of metal matrix composite. Russ. J. Non-Ferr. Met. 2014. Vol. 55. Iss. 2. P. 186—190.Tokova L.V., Zaitsev A.A., Kurbatkina V.V., Levashov E.A., Sidorenko D.A., Andreev V.A. The features of influence of ZrO2 and WC nanodispersed additives on the properties of metal matrix composite. Russ. J. Non-Ferr. Met. 2014. Vol. 55. Iss. 2. P. 186—190.Sidorenko D.A., Zaitsev A.A., Kirichenko A.N., Levashov E.A., Kurbatkina V.V., Loginov P.A., Rupasov S.I., Andreev V.A. Interaction of diamond grains with nanosized alloying agents in metal—matrix composites as studied by Ra-man spectroscopy. Diamond Relat. Mater. 2013. Vol. 38. P. 59—62.Sidorenko D.A., Zaitsev A.A., Kirichenko A.N., Levashov E.A., Kurbatkina V.V., Loginov P.A., Rupasov S.I., Andreev V.A. Interaction of diamond grains with nanosized alloying agents in metal—matrix composites as studied by Ra-man spectroscopy. Diamond Relat. Mater. 2013. Vol. 38. P. 59—62.Sidorenko D.A., Zaitsev A.A., Kirichenko A.N., Kurbatkina V.V., Levashov E.A., Sevast’yanov P.I., Rupasov S.I. Modification of the Fe—Cu—Co—Sn—P metal matrix with various forms of carbon nanomaterials. Russ. J. Non-Ferr. Met. 2015. Vol. 55. Iss. 6. P. 639—644.Sidorenko D.A., Zaitsev A.A., Kirichenko A.N., Kurbatkina V.V., Levashov E.A., Sevast’yanov P.I., Rupasov S.I. Modification of the Fe—Cu—Co—Sn—P metal matrix with various forms of carbon nanomaterials. Russ. J. Non-Ferr. Met. 2015. Vol. 55. Iss. 6. P. 639—644.Zaitsev A.A., Sidorenko D.A., Levashov E.A., Kurbatkina V.V., Rupasov S.I., Andreev V.A., Sevast’yanov P.V. Development and application of the Cu—Ni—Fe—Sn-based dispersion-hardened bond for cutting tools of superhard materials. J. Superhard Mater. 2012. Vol. 34. Iss. 4. P. 270—280.Zaitsev A.A., Sidorenko D.A., Levashov E.A., Kurbatkina V.V., Rupasov S.I., Andreev V.A., Sevast’yanov P.V. Development and application of the Cu—Ni—Fe—Sn-based dispersion-hardened bond for cutting tools of superhard materials. J. Superhard Mater. 2012. Vol. 34. Iss. 4. P. 270—280.Monteiro S.N., Skury A.L.D., de Azevedo M.G., Bobrovnitchii G.S. Cubic boron nitride competing with diamond as a superhard engineering material — an overview. J. Mater. Res. Technol. 2013. Vol. 2. Iss. 1. P. 68—74.Monteiro S.N., Skury A.L.D., de Azevedo M.G., Bobrovnitchii G.S. Cubic boron nitride competing with diamond as a superhard engineering material — an overview. J. Mater. Res. Technol. 2013. Vol. 2. Iss. 1. P. 68—74.Song Y., Nezu K., Park C.-H., Moriwaki T. Tool wear control in single-crystal diamond cutting of steel by using the ultra-intermittent cutting method. Int. J. Machine Tools Manufact. 2009. Vol. 49. Iss. 3—4. P. 339—343.Song Y., Nezu K., Park C.-H., Moriwaki T. Tool wear control in single-crystal diamond cutting of steel by using the ultra-intermittent cutting method. Int. J. Machine Tools Manufact. 2009. Vol. 49. Iss. 3—4. P. 339—343.Lane B.M., Shi M., Dow T.A., Scattergood R. Diamond tool wear when machining Al6061 and 1215 steel. Wear. 2010. Vol. 268. Iss. 11—12. P. 1434—1441.Lane B.M., Shi M., Dow T.A., Scattergood R. Diamond tool wear when machining Al6061 and 1215 steel. Wear. 2010. Vol. 268. Iss. 11—12. P. 1434—1441.Neo K.S., Rahman M., Li X.P., Khoo H.H., Sawa M., Maeda Y. Performance evaluation of pure CBN tools for machining of steel. J. Mater. Process. Technol. 2003. Vol. 140. Iss. 1—3. P. 326—331.Neo K.S., Rahman M., Li X.P., Khoo H.H., Sawa M., Maeda Y. Performance evaluation of pure CBN tools for machining of steel. J. Mater. Process. Technol. 2003. Vol. 140. Iss. 1—3. P. 326—331.Zaitsev A.A., Sidorenko D.A., Levashov E.A., Kurbatkina V.V., Andreev V.A., Rupasov S.I., Sevast’yanov P.V. Diamond tools in metal bonds dispersion-strengthened with nanosized particles for cutting highly reinforced concrete. J. Superhard Mater. 2010. Vol. 32. No. 6. P. 423—431.Zaitsev A.A., Sidorenko D.A., Levashov E.A., Kurbatkina V.V., Andreev V.A., Rupasov S.I., Sevast’yanov P.V. Diamond tools in metal bonds dispersion-strengthened with nanosized particles for cutting highly reinforced concrete. J. Superhard Mater. 2010. Vol. 32. No. 6. P. 423—431.Loginov P., Mishnaevsky Jr.L., Levashov E., Petrzhik M. Diamond and cBN hybrid and nanomodified cutting tools with enhanced performance: Development, testing and modeling. Mater. Design. 2015. Vol. 88. P. 310—319.Loginov P., Mishnaevsky Jr.L., Levashov E., Petrzhik M. Diamond and cBN hybrid and nanomodified cutting tools with enhanced performance: Development, testing and modeling. Mater. Design. 2015. Vol. 88. P. 310—319.Tillmann W., Ferreira M., Steffen A., Rüster K., Möller J., Bieder S., Paulus M., Tolan M. Carbon reactivity of binder metals in diamond—metal composites — characterization by scanning electron microscopy and X-ray diffraction. Diamond Relat. Mater. 2013. Vol. 38. P. 118—123.Tillmann W., Ferreira M., Steffen A., Rüster K., Möller J., Bieder S., Paulus M., Tolan M. Carbon reactivity of binder metals in diamond—metal composites — characterization by scanning electron microscopy and X-ray diffraction. Diamond Relat. Mater. 2013. Vol. 38. P. 118—123.De Oliveira L.J., Cabral S.C., Filgueira M. Study hot pressed Fe-diamond composites graphitization. Int. J. Refract. Met. Hard Mater. 2012. Vol. 35. P. 228—234.De Oliveira L.J., Cabral S.C., Filgueira M. Study hot pressed Fe-diamond composites graphitization. Int. J. Refract. Met. Hard Mater. 2012. Vol. 35. P. 228—234.Werninghaus T., Hahn J., Richter F., Zahn D.R.T. Raman spectroscopy investigation of size effects in cubic boron nitride. Appl. Phys. Lett. 1997. Vol. 70. P. 958—960.Werninghaus T., Hahn J., Richter F., Zahn D.R.T. Raman spectroscopy investigation of size effects in cubic boron nitride. Appl. Phys. Lett. 1997. Vol. 70. P. 958—960.Sachdev H. Influence of impurities on the morphology and Raman spectra of cubic boron nitride. Diamond Relat. Mater. 2003. Vol. 12. Iss. 8. P. 1275—1286.Sachdev H. Influence of impurities on the morphology and Raman spectra of cubic boron nitride. Diamond Relat. Mater. 2003. Vol. 12. Iss. 8. P. 1275—1286.Kutsay O., Yan C., Chong Y.M., Ye Q., Bello I., Zhang W.J., Zapien J.A., Zhou Z.F., Li Y.K., Garashchenko V., Gontar A.G., Novikov N.V., Lee S.T. Studying cubic boron nitride by Ra-man and infrared spectroscopies. Diamond Relat. Mater. 2010. Vol. 19. Iss. 7—9. P. 968—971.Kutsay O., Yan C., Chong Y.M., Ye Q., Bello I., Zhang W.J., Zapien J.A., Zhou Z.F., Li Y.K., Garashchenko V., Gontar A.G., Novikov N.V., Lee S.T. Studying cubic boron nitride by Ra-man and infrared spectroscopies. Diamond Relat. Mater. 2010. Vol. 19. Iss. 7—9. P. 968—971.Mermoux M., Jomard F., Tavarès C., Omnès F., Bustarret E. Raman characterization of boron-doped {111} homoepitaxial diamond layers. Diamond Relat. Mater. 2006. Vol. 15. Iss. 4—8. P. 572—576.Mermoux M., Jomard F., Tavarès C., Omnès F., Bustarret E. Raman characterization of boron-doped {111} homoepitaxial diamond layers. Diamond Relat. Mater. 2006. Vol. 15. Iss. 4—8. P. 572—576.Panov V.S., Chuvilin A.M. Tekhnologiya i svoistva spechennykh tverdykh splavov i izdelii iz nikh [Technology and properties of sintered hard alloys and their products]. Moscow: MISIS, 2001.Panov V.S., Chuvilin A.M. Tekhnologiya i svoistva spechennykh tverdykh splavov i izdelii iz nikh [Technology and properties of sintered hard alloys and their products]. Moscow: MISIS, 2001.Itoh H., Matsudaira T., Naka S., Hamamoto H., Obayashi M. Formation process of tungsten borides by solid state reaction between tungsten and amorphous boron. J. Mater. Sci. 1987. Vol. 22. P. 2811—2815.Itoh H., Matsudaira T., Naka S., Hamamoto H., Obayashi M. Formation process of tungsten borides by solid state reaction between tungsten and amorphous boron. J. Mater. Sci. 1987. Vol. 22. P. 2811—2815.

The authors declare that there are no conflicts of interest present.