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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">powder</journal-id><journal-title-group><journal-title xml:lang="ru">Известия вузов. Порошковая металлургия и функциональные покрытия</journal-title><trans-title-group xml:lang="en"><trans-title>Powder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1997-308X</issn><issn pub-type="epub">2412-8767</issn><publisher><publisher-name>НИТУ "МИСИС"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17073/1997-308X-2018-1-67-75</article-id><article-id custom-type="elpub" pub-id-type="custom">powder-349</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Наноструктурированные материалы и функциональные покрытия</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Nanostructured Materials and Functional Coatings</subject></subj-group></article-categories><title-group><article-title>ИССЛЕДОВАНИЕ СТРУКТУРЫ И МЕХАНИЗМА ОКИСЛЕНИЯ ПОКРЫТИЙ FEALCR/AL2O3, ПОЛУЧЕННЫХ ДЕТОНАЦИОННЫМ НАПЫЛЕНИЕМ</article-title><trans-title-group xml:lang="en"><trans-title>INVESTIGATION OF THE STRUCTURE AND OXIDATION MECHANISM OF FEALCR/AL2O3 DETONATION SPRAYED COATINGS</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Витязь</surname><given-names>П. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Vityaz</surname><given-names>P. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>академик, докт. техн. наук, проф., рук-ль аппарата НАН Беларуси</p><p>220072, Беларусь, г. Минск, пр. Независимости, 66</p></bio><bio xml:lang="en"><p>аcademician, Dr. Sci. (Tech.), prof., head of the Staff of the National Academy of Sciences of Belarus</p><p>220072, Belarus, Minsk, Nezavisimosti pr., 66</p></bio><email xlink:type="simple">vitiaz@presidium.bas-net</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Талако</surname><given-names>Т. Л.</given-names></name><name name-style="western" xml:lang="en"><surname>Talako</surname><given-names>T. L.</given-names></name></name-alternatives><bio xml:lang="ru"><p>докт. техн. наук, гл. науч. сотр. Института порошковой металлургии</p><p>220005, Беларусь, г. Минск, ул. Платонова, 41</p></bio><bio xml:lang="en"><p>Dr. Sci. (Tech.), principal researcher, Powder Metallurgy Institute</p><p>220005, Belarus, Minsk, Platonov str., 41).</p></bio><email xlink:type="simple">talako@tut.by</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Лецко</surname><given-names>А. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Letsko</surname><given-names>A. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. техн. наук, доцент, зав. лабораторией «Новые материалы и технологии» Института порошковой металлургии</p></bio><bio xml:lang="en"><p>Cand. Sci. (Tech.), associate prof., head of the laboratory «New materials and technologies», Powder Metallurgy Institute</p></bio><email xlink:type="simple">letsko@tut.by</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Парницкий</surname><given-names>Н. М.</given-names></name><name name-style="western" xml:lang="en"><surname>Parnitsky</surname><given-names>N. M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. техн. наук, доцент, зав. лабораторией «Новые материалы и технологии» Института порошковой металлургии</p></bio><bio xml:lang="en"><p>research assistant, Powder Metallurgy Institute</p></bio><email xlink:type="simple">letsko@tut.by</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Яковлева</surname><given-names>М. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Yakovleva</surname><given-names>M. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>науч. сотр. Института проблем материаловедения</p><p>03680, Украина, г. Киев, ул. Кржижановского, 3</p></bio><bio xml:lang="en"><p>researcher, Institute for Problems in Materials Science</p><p>03680, Ukraine, Kiev, Krzhyzhanovsky str., 3</p></bio><email xlink:type="simple">sirov78@ukr.net</email><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Президиум НАН Беларуси</institution><country>Беларусь</country></aff><aff xml:lang="en"><institution>National Academy of Sciences of Belarus</institution><country>Belarus</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Институт порошковой металлургии</institution><country>Беларусь</country></aff><aff xml:lang="en"><institution>Powder Metallurgy Institute</institution><country>Belarus</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Институт проблем материаловедения им. И.М. Францевича НАН Украины</institution><country>Украина</country></aff><aff xml:lang="en"><institution>Institute for Problems in Materials Science</institution><country>Ukraine</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2018</year></pub-date><pub-date pub-type="epub"><day>19</day><month>03</month><year>2018</year></pub-date><volume>0</volume><issue>1</issue><fpage>67</fpage><lpage>75</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Витязь П.А., Талако Т.Л., Лецко А.И., Парницкий Н.М., Яковлева М.С., 2018</copyright-statement><copyright-year>2018</copyright-year><copyright-holder xml:lang="ru">Витязь П.А., Талако Т.Л., Лецко А.И., Парницкий Н.М., Яковлева М.С.</copyright-holder><copyright-holder xml:lang="en">Vityaz P.A., Talako T.L., Letsko A.I., Parnitsky N.M., Yakovleva M.S.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://powder.misis.ru/jour/article/view/349">https://powder.misis.ru/jour/article/view/349</self-uri><abstract><p>Исследована стойкость к окислению покрытий, полученных детонационным напылением композиционного порошка FeAlCr/Al2O3, изготовленного методом механоактивируемого  самораспространяющегося высокотемпературного синтеза (MAСВС) с использованием  алюминотермических реакций восстановления оксидов. Порошок имеет достаточно однородную композиционную структуру, состоящую из легированного хромом  упорядоченного B2–FeAl и мелких включений α-Cr2O3 и α-Al2O3. У детонационных  покрытий, напыленных на основу из нержавеющей стали, наблюдалась типичная слоистая  структура без трещин и отслоений. Толщина покрытий составляла 250–300 мкм,  микротвердость находилась в пределах 5,9–6,1 ГПа. Покрытия из синтезированного  порошка в основном наследуют его структуру и фазовый состав, хотя в процессе напыления происходит некоторое окисление алюминия и хрома. Изучены особенности циклического и изотермического окисления полученных покрытий в воздушной атмосфере в диапазоне  температур 900–1000 °С. Установлено, что стойкость к окислению детонационных покрытий из синтезированного порошка в результате окисления на воздухе при температуре 950 °C в  течение 48 ч близка к стойкости к окислению покрытий, полученных из порошка FeAl– FexAly с содержанием алюминия 45 мас.%. В то же время коэффициент температурного  линейного расширения (КТЛР) покрытий FeAlCr/Al2O3 ближе к КТЛР материала основы, а их  сопротивление ползучести выше, чем у него, за счет присутствия тонких включений  тугоплавких оксидов. Предполагается, что α-Cr, Cr2O3 и множество мелких включений  оксида алюминия, присутствующих в синтезированном порошке и формирующихся в  процессе напыления, ускоряют образование защитной пленки, подавляя зарождение и рост  гематита на ранних стадиях окисления при температурах до 950 °С.</p></abstract><trans-abstract xml:lang="en"><p>Oxidation resistance of detonation sprayed coatings obtained from FeAlCr/Al2O3 powder produced by the method of mechanically assisted self-propagating high-temperature synthesis  (MASHS) using aluminothermic reactions has been investigated. The powder has a sufficiently homogeneous composite structure  consisting of chromium-alloyed ordered B2–FeAl and fine inclusions of α-Cr2O3 and α-Al2O3. Detonation coatings sprayed on  a stainless steel substrate have a typical layered coating structure  without cracks or spalling. The coating thickness is 250–300 μm,  microhardness is 5,9–6,1 GPa. Coatings of a synthesized powder  mainly inherit its structure and phase composition although some  aluminum and chromium oxidation takes place when spraying. The features of cyclic and isothermal oxidation of the obtained  coatings in air within a temperature range of 900–1000 °C have  been studied. The oxidation resistance of synthesized powder detonation coatings after 48 h of oxidation in air at 950 °C is close to that of coatings obtained from FeAl–FexAly powder with an  aluminum content of 45 wt.%. At the same time, the coefficient of  linear  thermal expansion of FeAlCr/Al2O3 coatings is closer to that  of the substrate, and their creep resistance is higher as compared  with the substrate due to the presence of fine inclusions of refractory oxides. α-Cr, Cr2O3 and a lot of fine alumina inclusions present in the synthesized powder and formed when spraying are supposed to  accelerate the protective film formation while suppressing the nucleation and growth of hematite at early oxidation stages at  temperatures up to 950 °C. </p></trans-abstract><kwd-group xml:lang="ru"><kwd>интерметаллид</kwd><kwd>композиционный порошок</kwd><kwd>механоактивируемый самораспространяющийся высоко- температурный синтез (МАСВС)</kwd><kwd>детонационное покрытие</kwd></kwd-group><kwd-group xml:lang="en"><kwd>intermetallic</kwd><kwd>composite powder</kwd><kwd>mechanically assisted self-propagating high-temperature synthesis (MASHS)</kwd><kwd>D-gun coatings.</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Stoloff N.S. 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