powderИзвестия вузов. Порошковая металлургия и функциональные покрытияPowder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya)1997-308X2412-8767НИТУ "МИСИС"10.17073/1997-308X-2018-3-41-45powder-383Research ArticleСамораспространяющийся высокотемпературный синтез (СВС)Self-Propagating High-Temperature Synthesis (SHS)Соединение керамических материалов с танталовой подложкой в условиях самораспространяющегося высокотемпературного синтезаSHS-aided joining of ceramics with Ta substrateКамынинаО. К.KamyninaO. K.

Кандидат физико-математических наук, ученый секретарь ИСМАН.

142432, Московская обл., Черноголовка, ул. Академика Осипьяна, 8

Cand. Sci. (Phys.-Math.), Secretary for science ISMAN.

142432, Moscow Region, Chernogolovka, Academician Osipyan str., 8

sci-secretary@ism.ac.ruВадченкоС. Г.VadchenkoS. G.

Кандидат физико-математических наук, ведущий научный сотрудник лаборатории динамики микрогетерогенных процессов ИСМАН.

142432, Московская обл., Черноголовка, ул. Академика Осипьяна, 8

Cand. Sci. (Phys.-Math.), Leading researcher, Laboratory of the dynamics of microheterogeneous processes ISMAN.

142432, Moscow Region, Chernogolovka, Academician Osipyan str., 8

vadchenko@ism.ac.ruЩукинА. С.ShchukinA. S.

Научный сотрудник лаборатории динамики микрогетерогенных процессов ИСМАН.

142432, Московская обл., Черноголовка, ул. Академика Осипьяна, 8

Researcher, Laboratory of the dynamics of microheterogeneous processes ISMAN.

142432, Moscow Region, Chernogolovka, Academician Osipyan str., 8

shchukin@ism.ac.ruИнститут структурной макрокинетики и проблем материаловедения им. А. Мержанова РАНРоссияMerzhanov Institute of Structural Macrokinetics and Materials Science Russian Academy of SciencesRussian Federation201817092018034145Copyright © Камынина О.К., Вадченко С.Г., Щукин А.С., 20182018Камынина О.К., Вадченко С.Г., Щукин А.С.Kamynina O.K., Vadchenko S.G., Shchukin A.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://powder.misis.ru/jour/article/view/383

Проведены эксперименты по оценке возможности соединения керамических материалов с танталовой подложкой в условиях самораспространяющегося высокотемпературного синтеза (СВС). Образец формировался из танталовых фольг и таблеток Ti + 0,65C и 5Ti + 3Si, между которыми была проложена поджигающая ленточка состава Ti + 2B. Образец устанавливался на подставку из нитрида бора. Для уменьшения теплоотвода на него сверху помещалась пластина из шамотного кирпича (SiO2 + Al2O3), на который устанавливался груз массой 3360 Эксперименты проводились в реакционной камере в среде аргона под давлением 1 атм. Образцы предварительно подогревались снизу, затем реакция инициировалась с их торцевой части. Температуры образцов измерялись W–Re-термопарами. Градиент температуры по толщине образца в зависимости от скорости нагрева составлял 50–150 град/мм. Получены образцы с прочным соединением танталовой фольги с Ti + 0,65C и хорошим соединением двух таблеток. Верхняя фольга не приварилась к таблетке 5Ti + 3Si, что объясняется достаточно низкой температурой (1600 °C) в месте соединения. При изучении соединения танталовой фольги с карбидом титана обнаружено формирование промежуточных слоев Ti–Ta и (Ta,Ti)C. В результате проведенных исследований показана возможность соединения танталовой фольги с керамическими материалами в ходе СВС. Основными условиями такого соединения является наличие жидкой фазы и соответствие температуры горения состава Ti + 0,65C температуре плавления танталовой подложки. Полученные результаты могут быть полезны при получении многослойных функциональных покрытий и функционально-градиентных материалов.

The possibility of joining ceramic materials with a Ta substrate was explored in the conditions of self-propagating high-temperature synthesis (SHS). The sample used in experiments consisted of Ta foils, Ti + 0,65C pellet, 5Ti + 3Si pellet, and a Ti + 2B igniting tape laid between them. The sample was installed onto a BN base and covered by a chamotte brick (SiO2 + Al2O3) plate with a weight of 3,36 kg placed on top in order to reduce heat sink. Experiments were performed in a closed reactor under 1 atm of Ar. Samples were preheated from the bottom, after which SHS reaction was initiated from the butt. Temperature was monitored with three W/Re thermocouples. Depending on heating rate, temperature gradient along the sample depth had a value of 50–150 deg/mm. The samples obtained exhibited strong joining between Ta foil and Ti + 0,65C and also between the two pellets. The upper foil did not stick to the 5Ti + 3Si pellet, which can be explained by low temperature at the interface (1600 °C). At the Ta–TiC interface, the formation of Ti–Ta and (Ti, Ta)C interlayers was observed. The studies conducted demonstrate the possibility of Ta foil joining with ceramic materials under SHS conditions. Main conditions for this joint are the presence of a liquid phase and Ti + 0,65C combustion temperature matching the Ta substrate melting temperature. The results may be useful for deposition of multilayer functional coatings and functionally graded materials.

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The authors declare that there are no conflicts of interest present.