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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">powder</journal-id><journal-title-group><journal-title xml:lang="ru">Известия вузов. Порошковая металлургия и функциональные покрытия</journal-title><trans-title-group xml:lang="en"><trans-title>Powder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1997-308X</issn><issn pub-type="epub">2412-8767</issn><publisher><publisher-name>НИТУ "МИСИС"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17073/1997-308X-2023-3-67-78</article-id><article-id custom-type="elpub" pub-id-type="custom">powder-829</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Наноструктурированные материалы и функциональные покрытия</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Nanostructured Materials and Functional Coatings</subject></subj-group></article-categories><title-group><article-title>Покрытия на основе карбида тантала, полученные методами магнетронного распыления и электроискрового легирования, для повышения износостойкости деталей запорной арматуры</article-title><trans-title-group xml:lang="en"><trans-title>TaC-based wear-resistant coatings obtained by magnetron sputtering and electro-spark deposition for wedge gate valve protection</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-8668-5877</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Сытченко</surname><given-names>А. Д.</given-names></name><name name-style="western" xml:lang="en"><surname>Sytchenko</surname><given-names>A. D.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Алина Дмитриевна Сытченко – мл. науч. сотрудник лаборатории «In situ диагностика структурных превращений» научно-учебного центра (НУЦ) СВС, МИСИС–ИСМАН</p><p>Россия, 119049, г. Москва, Ленинский пр-т, 4 стр. 1</p></bio><bio xml:lang="en"><p>Alina D. Sytchenko – Junior Research Scientist of the Laboratory “In situ Diag­nostics of Structural Transformations” of Scientific-Educa­tional Center of Self-Propagating High-Temperature Synthesis (SHS-Center)</p><p>4 bld. 1 Leninskiy Prosp., Moscow 119049, Russia</p></bio><email xlink:type="simple">alina-sytchenko@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-6817-5999</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Фатыхова</surname><given-names>М. Н.</given-names></name><name name-style="western" xml:lang="en"><surname>Fatykhova</surname><given-names>M. N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Мария Николаевна Фатыхова – мл. науч. сотрудник лаборатории «In situ диагностика структурных превращений» НУЦ СВС</p><p>Россия, 119049, г. Москва, Ленинский пр-т, 4 стр. 1</p></bio><bio xml:lang="en"><p>Maria N. Fatykhova – Junior Research Scientist of the Laboratory  “In situ Diagnostics of Structural Transformations” of SHS-Center</p><p>4 bld. 1 Leninskiy Prosp., Moscow 119049, Russia</p></bio><email xlink:type="simple">mariya.antonyuck@ya.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-8949-6345</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кузнецов</surname><given-names>В. П.</given-names></name><name name-style="western" xml:lang="en"><surname>Kuznetsov</surname><given-names>V. P.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Виктор Павлович Кузнецов – д.т.н., профессор кафедры термообработки и физики металлов</p><p>Россия, 620075, г. Екатеринбург, ул. Мира, 19</p></bio><bio xml:lang="en"><p>Victor P. Kuznetsov – Dr. Sci. (Eng.), Prof., Department of Heat Treatment and Physics of Metals</p><p>19 Mira Str., Yekaterinburg 620002, Russia</p></bio><email xlink:type="simple">wpkuzn@mail.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-2585-0733</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Купцов</surname><given-names>К. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Kuptsov</surname><given-names>K. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Константин Александрович Купцов – к.т.н., ст. науч. сотрудник НУЦ СВС</p><p>Россия, 119049, г. Москва, Ленинский пр-т, 4 стр. 1</p></bio><bio xml:lang="en"><p>Konstantin A. Kuptsov – Cand. Sci. (Eng.), Senior Researcher of SHS-Center</p><p>4 bld. 1 Leninskiy Prosp., Moscow 119049, Russia</p></bio><email xlink:type="simple">kuptsov.k@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-1736-8050</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Петржик</surname><given-names>М. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Petrzhik</surname><given-names>M. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Михаил Иванович Петржик – д.т.н., профессор кафедры порошковой металлургии и функциональных покрытий НИТУ МИСИС; вед. науч. сотрудник лаборатории «In situ диагностика структурных превращений» НУЦ СВС</p><p>Россия, 119049, г. Москва, Ленинский пр-т, 4 стр. 1</p></bio><bio xml:lang="en"><p>Mikhail I. Petrzhik – Dr. Sci. (Eng.), Prof., Department of Powder Metallurgy and Functional Coatings, NUST MISIS; Leading Researcher of the Laboratory «In situ diagnostics of structural transformations” of SHS-Center</p><p>4 bld. 1 Leninskiy Prosp., Moscow 119049, Russia</p></bio><email xlink:type="simple">mi_p@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-6222-4497</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кудряшов</surname><given-names>А. Е.</given-names></name><name name-style="western" xml:lang="en"><surname>Kudryashov</surname><given-names>A. E.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Александр Евгеньевич Кудряшов – к.т.н., вед. науч. сотрудник лаборатории «In situ диагностика структурных превращений» НУЦ СВС</p><p>Россия, 119049, г. Москва, Ленинский пр-т, 4 стр. 1</p></bio><bio xml:lang="en"><p>Alexander E. Kudryashov – Cand. Sci. (Eng.), Leading Researcher of the Laboratory «In situ diagnostics of structural transformations” of SHS-Center</p><p>4 bld. 1 Leninskiy Prosp., Moscow 119049, Russia</p></bio><email xlink:type="simple">aekudr@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-1635-4746</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кирюханцев-Корнеев</surname><given-names>Ф. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Kiryukhantsev-Korneev</surname><given-names>Ph. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Филипп Владимирович Кирюханцев-Корнеев – д.т.н., доцент кафедры порошковой металлургии и функциональных покрытий НИТУ МИСИС; зав. лабораторией «In situ диагностика структурных превращений» НУЦ СВС</p><p>Россия, 119049, г. Москва, Ленинский пр-т, 4 стр. 1</p></bio><bio xml:lang="en"><p>Philipp V. Kiryukhantsev-Korneev – Dr. Sci. (Eng.), Associate Prof., Department of Powder Metallurgy and Functional Coatings, NUST MISIS; Head of the Laboratory «In situ diagnostics of structural transformations” of SHS-Center</p><p>4 bld. 1 Leninskiy Prosp., Moscow 119049, Russia</p></bio><email xlink:type="simple">kiruhancev-korneev@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Национальный исследовательский технологический университет «МИСИС»</institution><country>Россия</country></aff><aff xml:lang="en"><institution>National University of Science and Technology “MISIS”</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Уральский федеральный университет имени первого Президента России Б.Н. Ельцина</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Ural Federal University named after the First President of Russia B.N. Yeltsin</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2023</year></pub-date><pub-date pub-type="epub"><day>23</day><month>09</month><year>2023</year></pub-date><volume>17</volume><issue>3</issue><fpage>67</fpage><lpage>78</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Сытченко А.Д., Фатыхова М.Н., Кузнецов В.П., Купцов К.А., Петржик М.И., Кудряшов А.Е., Кирюханцев-Корнеев Ф.В., 2023</copyright-statement><copyright-year>2023</copyright-year><copyright-holder xml:lang="ru">Сытченко А.Д., Фатыхова М.Н., Кузнецов В.П., Купцов К.А., Петржик М.И., Кудряшов А.Е., Кирюханцев-Корнеев Ф.В.</copyright-holder><copyright-holder xml:lang="en">Sytchenko A.D., Fatykhova M.N., Kuznetsov V.P., Kuptsov K.A., Petrzhik M.I., Kudryashov A.E., Kiryukhantsev-Korneev P.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://powder.misis.ru/jour/article/view/829">https://powder.misis.ru/jour/article/view/829</self-uri><abstract><p>Покрытия Ta–Zr–Si–B–C осаждались методом магнетронного распыления (МР) многокомпонентной мишени TaSi2–Ta3B4–(Ta, Zr)B2 в среде Ar + C2H4 . Покрытия на основе TaC–Fe–Cr–Mo–Ni были получены путем электроискрового легирования (ЭИЛ) с использованием электрода TaC–Cr–Mo–Ni. Состав и структура покрытий исследовались с помощью сканирующей электронной микроскопии, энергодисперсионной спектроскопии, оптической эмиссионной спектроскопии тлеющего разряда и рентгенофазового анализа. Механические характеристики определялись методом наноиндентирования. Трибологические свойства исследовались на машине трения в режиме возвратно-поступательного движения. Выявлено, что покрытия обладают однородной бездефектной структурой и основной структурной составляющей является ГЦК-фаза TaC. Ее концентрация в МР-покрытии на 30 % выше, чем в ЭИЛ- покрытии. Размеры кристаллитов TaC для МР- и ЭИЛ-покрытий составляли 3 и 30 нм соответственно. Высокая доля карбидной фазы и малый размер кристаллитов обеспечили более высокую твердость МР-покрытия (Н = 28 ГПа) по сравнению с ЭИЛ-образцом (Н = 10 ГПа). Покрытия характеризовались близкими значениями коэффициента трения (около 0,15) и приведенного износа (&lt;10–7 мм3/(Н·м)). Осаждение на стальную подложку привело к снижению коэффициента трения в 5 раз и приведенного износа на 4 порядка. Проведены опытно-промышленные испытания покрытий, осажденных на клиновые задвижки запорной арматуры для перекачки жидкости, используемые в нефтегазовой промышленности. Результаты испытаний показали, что ресурс работы стальной клиновой задвижки возрос на 25 и 70 % при осаждении МР- и ЭИЛ-покрытий соответственно.</p></abstract><trans-abstract xml:lang="en"><p>Ta–Zr–Si–B–C coatings were deposited by magnetron sputtering (MS) of a TaSi2–Ta3B4–(Ta, Zr)B2 multi-component target in an Ar + C2H4 gas mixture. TaC–Cr–Mo–Ni based coatings were obtained by electro-spark deposition (ESD) using TaC–Cr–Mo–Ni electrode. The composition and structure of the coatings were studied using scanning electron microscopy, energy-dispersive spectroscopy, glow discharge optical emission spectroscopy and X-ray diffraction. Mechanical and tribological properties of coatings were determined using nanoindentation and pin-on-disk tests. The study showed that the coatings have a homogeneous and defect-free structure, with the main structural component being the fcc-TaC phase. The MS coating exhibited a 30 % higher concentration of the TaC phase compared to the ESD coating. The TaC crystallite sizes for the MS and ESD coatings were 3 and 30 nm, respectively. The presence of a high fraction of the carbide phase and small crystallite size for the MS coating resulted in superior hardness (H = 28 GPa) compared to the ESD sample (H = 10 GPa). Both coatings exhibited similar values of the friction coefficient (about 0.15) and demonstrated reduced wear rates (&lt;10–7 mm3/(N·m)). The deposition of coatings on a steel substrate led to a decrease in the friction coefficient by five times and the wear rate by four orders of magnitude. Pilot tests were conducted on coatings applied to wedge gate valve of shut-off devices used in the oil and gas industry for pumping liquids. The results indicated that the service life of the steel wedge gate valve increased by 25 and 70 % with deposited MS and ESD coatings, respectively.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>магнетронное распыление (МР)</kwd><kwd>электроискровое легирование (ЭИЛ)</kwd><kwd>покрытия</kwd><kwd>TaС</kwd><kwd>коэффициент трения</kwd><kwd>износостойкость</kwd></kwd-group><kwd-group xml:lang="en"><kwd>magnetron sputtering</kwd><kwd>electro-spark deposition</kwd><kwd>coatings</kwd><kwd>TaC</kwd><kwd>friction coefficient</kwd><kwd>wear resistance</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Работа выполнена при финансовой поддержке Российского научного фонда (проект № 23-49-00141).</funding-statement><funding-statement xml:lang="en">This work was performed with financial support by Russian Science Foundation (project no. 23-49-00141).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Barile C., Casavola C., Pappalettera G., Renna G. 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