Investigation into Absorption Properties of Ultradispersed Powder of the Alloy with the Composition Al–1,5%Ca–1,5%La before and after Treatment with Water
https://doi.org/10.17073/1997-308X-2015-2-3-7
Abstract
The dispersed composition and morphology of the particles of metal powders of the composition Al–1,5%Ca–1,5%La before and after interaction with water are investigated using a complex of methods including low-temperature nitrogen adsorption, scanning electron microscopy, X-ray phase analysis, etc. It is shown that the treatment of this metallic powder with water leads to the formation of slit-like and cylindrical pores in interaction products. The specific surface increases from 9 to 182 m2/g in this case. It is confirmed by the X-ray phase analysis that thermal treatment of aluminum powders right up to 200 °C leads to the formation of the particles of gel-like boehmite AlOOH on the surface. The results of investigations showed that hydrotreating allows one to vary the texture characteristics of ultradispersed powder.
About the Authors
A. V. RyabinaRussian Federation
kand. khim. nauk, nauch. sotr. laboratorii fizikokhimii dispersnykh sistem IKhTT UrO RAN (620219 g. Ekaterinburg, ul. Pervomaiskaya, 91).
V. G. Shevchenko
Russian Federation
dokt. khim. nauk, zav. laboratorii fizikokhimii dispersnykh sistem IKhTT UrO RAN (620219 g. Ekaterinburg, ul. Pervomaiskaya, 91).
References
1. Ryabina A.V., Shevchenko V.G., Eselevich D.A. // Nanosystems: Physics, Chemistry, Mathematics. 2014. Vol. 5 (4). P. 597—602.
2. Шевченко В.Г., Латош И.Н., Чупова И.А. и др. // Перспективные материалы. 2010. № 1. С. 1—8.
3. Каблов Е.Н., Сидоров В.В. // Перспективные материалы. 2001. № 1. С. 23—34.
4. Данчевская М.Н., Торбин С.Н. и др. // Вестник Московского университета. Сер. 2. Химия. 2002. Т. 43, № 5. С. 288—290.
5. Рябина А.В., Кононенко В.И. // Изв. вузов. Порошковая металлургия и функциональные покрытия. 2014. № 2. С. 3—7.
6. Рябина А.В., Кононенко В.И., Торокин В.В. // Металлы. 2013. № 5. С. 9—12.
7. Шевченко В.Г., Малашин С.И., Латош И.А. и др. // Перспективные материалы. 2010. № 1. C. 68—75.
8. Строение и свойства адсорбентов и катализаторов / Под ред. Б.Г. Линсена. М.: Мир, 1973.
9. Грегг С., Синг К. Адсорбция, удельная поверхность, пористость. М.: Мир, 1984.
10. Фенелонов В.Б. Пористый углерод: Новосибирск: Институт катализа СО РАН, 1995.
11. Чалый В.П. Гидроокиси металлов: Закономерности образования, состав, структура и свойства. Киев: Наук. думка, 1972.
Review
For citations:
Ryabina A.V., Shevchenko V.G. Investigation into Absorption Properties of Ultradispersed Powder of the Alloy with the Composition Al–1,5%Ca–1,5%La before and after Treatment with Water. Powder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya). 2015;(2):3-7. (In Russ.) https://doi.org/10.17073/1997-308X-2015-2-3-7