EVALUATION OF THERMAL STABILITY OF MULTILAYER NANOSTRUCTURED COATINGS BY ANALYZING DIFFUSION MOBILITY OF LAYER COMPONENTS
https://doi.org/10.17073/1997-308X-2016-4-86-93
Abstract
The thermal stability of multilayer nanostructured coatings is investigated by analyzing the diffusion mobility of layer components. The paper studies in detail the possibility of increasing the thermal stability of multilayer coatings based on mutually-soluble Ti–Al–N and Cr–N layers by introducing an additional Zr–N-based barrier layer into the multilayer nanostructure. The calculated coefficients of basic coating metal element diffusion into the corresponding nitride layers when heating to 800–1000 °C show no significant diffusion blur of layer boundaries in the presence of a Zr–N-based barrier layer. Thus, its introduction reduces their values (obtained at t = 1000 °C, cm2/s: DCr/TiN = 5·10–17, DCr/ZrN = 2·10–18; DTi/Cr2N = 9·10–18, DTi/ZrN = 3·10–18). Physical and mechanical properties of the coatings are not changed during vacuum annealing at t < 900 °C but significantly degrade as the annealing temperature rises further due to the degradation of the multilayer structure of coatings during their annealing.
About the Authors
A. O. Volkhonskii
NUST «MISIS
Russian Federation
Cand. Sci. (Tech.), senior lecturer, Department of functional nanosystems and high-temperature materials (FNS&HTM) of the National University of Science and Technology
Russian Federation
Cand. Sci. (Tech.), senior lecturer, Department of functional nanosystems and high-temperature materials (FNS&HTM) of the National University of Science and Technology
I. V. Blinkov
NUST «MISIS
Russian Federation
Dr. Sci. (Tech.), prof., Department of FNS&HTM
Russian Federation
Dr. Sci. (Tech.), prof., Department of FNS&HTM
Yu. V. Levinsky
Moscow Technological University
Russian Federation
Dr. Sci. (Tech.), prof., Department of chemistry and technology of rare and scattered elements, and nanoscale composite materials, MITHT
Russian Federation
Dr. Sci. (Tech.), prof., Department of chemistry and technology of rare and scattered elements, and nanoscale composite materials, MITHT
E. A. Skryleva
NUST «MISIS
Russian Federation
scientific researcher, Department of materials science of semiconductors and dielectrics
Russian Federation
scientific researcher, Department of materials science of semiconductors and dielectrics
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Review
For citations:
Volkhonskii A.O., Blinkov I.V., Levinsky Yu.V., Skryleva E.A. EVALUATION OF THERMAL STABILITY OF MULTILAYER NANOSTRUCTURED COATINGS BY ANALYZING DIFFUSION MOBILITY OF LAYER COMPONENTS. Powder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya). 2016;(4):86-93. (In Russ.) https://doi.org/10.17073/1997-308X-2016-4-86-93
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