Hard wear-resistant TiAlSiCN/MoSeC coatings with low coefficient of friction at room and elevated temperatures
https://doi.org/10.17073/1997-308X-2013-4-60-67
Abstract
TiAlSiCN and TiAlSiCN/MoSeC coatings have been produced by magnetron sputtering of segmented SHS- and compacted powdered targets. The struc- ture and composition of the coatings have been investigated by X-ray phase analysis, X-ray photoelectron spectroscopy, Raman spectroscopy, trans- mission electron microscopy, and light spectroscopy. The base of TiAlSiCN coating composes of FCC-phase with crystallites of < 15 nm in size; in sput- tering of TiAlSiCN and MoSeC segments in 3 : 1 ratio, decrease of crystallites size takes place and in 2 : 2 ratio does the amorphisation. MoSe2 phase is found also in TiAlSiCN/MoSeC coatings. It follows from the results of nanoindentation that hardness of TiAlSiCN coatings is 40 GPa, TiAlSiCN/MoSeC coatings – 28 GPa and 12 GPa at 3 : 1 and 2 : 2 ratios respectively. The coefficient of friction of TiAlSiCN coatings is 0,75 at ambient temperature, after in- troduction of MoSeC it drops to 0,05; wear resistance of coatings raises as well. In tribological tests of TiAlSiCN/MoSeC coatings with continuous heat- ing, low coefficient of friction (< 0,1) is unchanged up to 300 °C.
About the Authors
A. V. Bondarev
Национальный исследовательский технологический университет «МИСиС», 119049, г. Москва, В-49, Ленинский пр-т, 4
Russian Federation
Russian Federation
F. V. Kiryukhantsev-Korneyev
Национальный исследовательский технологический университет «МИСиС», 119049, г. Москва, В-49, Ленинский пр-т, 4
Russian Federation
Russian Federation
D. V. Shtansky
Национальный исследовательский технологический университет «МИСиС», 119049, г. Москва, В-49, Ленинский пр-т, 4
Russian Federation
Russian Federation
References
1. Левашов Е. А., Штанский Д. В. // Успехи химии. 2007. No 76 (5). С. 501.
2. Shtansky D. V., Kuptsov K. A., Kiryukhantsev-Korneev Ph.V. et al. // Surf. Coat. Technol. 2011. Vol. 205. P. 4640.
3. Muratore C., Voevodin A. A. // Annu. Rev. Mater. Res. 2009. Vol. 39. P. 297.
4. Shtansky D. V., Sheveyko A. N., Sorokin D. I. et al. // Surf. Coat. Technol. 2008. Vol. 202. P. 5953.
5. Shtansky D. V., Kuptsov K. A., Kiryukhantsev-Korneev Ph. V., Sheveiko A. N. // Ibid. 2012. Vol. 206. P. 4840.
6. Kuptsov K. A., Kiryukhantsev-Korneev Ph. V., Sheveiko A. N., Shtansky D. V. // Ibid. 2013. Vol. 216. P. 273.
7. Левашов Е. А., Погожев Ю. С., Рогачев А. С. и др. // Изв. вузов. Порошк. металлургия и функц. покрытия. 2010. No 3. С. 26.
8. Oliver W. C., Pharr G. M. // J. Mater. Res. 1992. Vol. 7. P. 1564.
9. Pharr G. // Mater. Sci. 1998. Vol. 253. Р.151.
10. Ding X., Zeng X. T., Goto T. // Surf. Coat. Technol. 2005. Vol. 198. P. 432.
11. Polcar T., Evaristo M., Stueber M., Cavaleiro A. // Surf. Coat. Technol. 2008. Vol. 202. P. 2418.
12. Polcar T., Cavaleiro A. // Ibid. 2011. Vol. 206. P. 686.
13. Dreiling I., Haug A., Holzschuh H., Chasse T. // Ibid. 2009. Vol. 204. P. 1008.
14. Escobar-Alarcon L., Camps E., Romero S. et al. // Appl. Phys. A. 2010. Vol. 101. P. 771.
15. Voevodin A. A., Zabinski J. S. // Wear. 2006. Vol. 61. P. 1285.
16. Fominski V. Yu., Romanov R. I., Gusarov A.V., Celis J.-P. // Surf. Coat. Technol. 2007. Vol. 201. P. 7813.
17. MalloukyA.,BernedeJ.C.//ThinSolidFilms.1988.Vol.158.P.285.
18. Polcar T., Evaristo M., Colac R. et al. // Acta Mater. 2008. Vol. 56. P. 5101.
19. Matthews D. T. A., Ocelik V., Bronsveld P. M., De Hosson J. Th. M. // Ibid. P. 1762.
20. Voevodin A. A., O’Neill J. P., Zabinski J. S. // Surf. Coat. Technol. 1999. Vol. 116. P. 36.
21. Gilmore R., Baker M. A., Gibson P. N. et al. // Ibid. 1998. Vol. 108–109. P. 345.
22. Martínez-Martínez D., López-Cartes C., Fernández A., Sánchez-López J. C. // Ibid. 2008. Vol. 203. P. 756.
23. Bae Y. W., Lee W. Y., Besmann T. M. et al. // Mater. Sci. Eng. 1996. Vol. 209. P. 372.
24. Kubart T., Polcar T., Kopecky L. et al. // Surf. Coat. Technol. 2005. Vol. 193. P. 230.
25. Polcar T., Evaristo M., Stueber M., Cavaleiro A. // Wear. 2009. Vol. 266. P. 393.
Review
For citations:
Bondarev A.V., Kiryukhantsev-Korneyev F.V., Shtansky D.V. Hard wear-resistant TiAlSiCN/MoSeC coatings with low coefficient of friction at room and elevated temperatures. Powder Metallurgy аnd Functional Coatings (Izvestiya Vuzov. Poroshkovaya Metallurgiya i Funktsional'nye Pokrytiya). 2013;(4):60-67. (In Russ.) https://doi.org/10.17073/1997-308X-2013-4-60-67
Views:
837
Email this article 